The publications listed below were either co-authored by a member of the facility, or data contained within the paper was collected using one of the instruments within our facility.
2021
- Zirconium and hafnium polyhedral oligosilsesquioxane complexes – green homogeneous catalysts in the formation of bio-derived ethers via a MPV/etherification reaction cascade
- Synthesis, structures and catalytic activity of some BINOL based boronates and boronium salts
- Solid-state behaviors of imines: colossal biaxial positive thermal expansion, motion capability, and phase transitions
- Positive thermal expansion facilitates the formation of argentophilic forces following an order–disorder phase transition
- Cobalt- and iron-catalyzed regiodivergent alkene hydrosilylations
- Honeycomb molecular network based upon a hydrate of 4,6-dichlororesorcinol and the photoproduct rtct-tetrakis(pyridin-4-yl)cyclobutane
- Cocrystallization of Trimethoprim and Solubility Enhancement via Salt Formation
- Controlling Topology within Halogen-Bonded Networks by Varying the Regiochemistry of the Cyclobutane-Based Nodes
- Self-Assembly of Complementary Components Using a Tripodal Bismuth Compound: Pnictogen Bonding or Coordination Chemistry?
- Thermal Expansion Properties and Mechanochemical Synthesis of Stoichiometric Cocrystals Containing Tetrabromobenzene as a Hydrogen‐ and Halogen‐Bond Donor
- Triple-Columned and Multiple-Layered 3D Polymers: Design, Synthesis, Aggregation-Induced Emission (AIE), and Computational Study
- Small Molecule Activation with Intramolecular "Inverse" Frustrated Lewis Pairs
- Asymmetric Catalytic Approach to Multilayer 3D Chirality
- Carbon monoxide bond cleavage mediated by an intramolecular frustrated Lewis pair: access to new B/N heterocycles via selective incorporation of single carbon atoms
- Influence of heterocyclic N-donors on the structural topologies and vibrational spectra of uranyl selenate phases
- Iodoperchlorobenzene acts as a dual halogen-bond donor to template a [2+2] cycloaddition reaction within an organic co-crystal
- Asymmetric synthesis of functionalized 2,3-dihydrobenzofurans using salicyl N-phosphonyl imines facilitated by group-assisted purification (GAP) chemistry
- Asymmetric [4+2] cycloaddition synthesis of 4H-chromene derivatives facilitated by group-assisted-purification (GAP) chemistry
- Surface modifications of plasma treated aluminum particles and direct evidence for altered reactivity
- Tailoring Thermal Transport Properties by Inducing Surface Oxidation Reactions in Bulk Metal Composites
- Regulating magnesium combustion using surface chemistry and heating rate
- Thermal oxidation analysis of aerosol synthesized fuel particles composed of Al versus Al-Si
- Multi-scale pseudoelasticity of NiTi alloys fabricated by laser additive manufacturing
- The reinforcement mechanisms of graphene oxide in laser-directed energy deposition fabricated metal and ceramic matrix composites: a comparison study
- Fabrication of a TiC-Ti Matrix Composite Coating Using Ultrasonic Vibration-Assisted Laser Directed Energy Deposition: The Effects of Ultrasonic Vibration and TiC Content
- An investigation on Ni4Ti3 phase precipitation and its effects in laser directed energy deposition of TiC-NiTi composites
2020
- Thermal oxidation analysis of aerosol synthesized fuel particles composed of Al versus Al-Si
- Synthesis of metal iodates from an energetic salt
- Thermal analysis of microscale aluminum particles coated with perfluorotetradecanoic (PFTD) acid
- Synthesis and characterization of polymeric films with stress-altered aluminum particle fillers
- Thermal analysis of an iodine rich binder for energetic material applications
- Aluminum particle reactivity as a function of alumina shell structure: Amorphous versus crystalline
- Ultrasonic vibration-assisted laser directed energy deposition in-situ synthesis of NiTi alloys: Effects on microstructure and mechanical properties
- Investigating effects of temperature and confining pressure on dynamic elastic properties and permeability—An experimental study
- An experimental investigation of cryogenic treatments effects on porosity, permeability, and mechanical properties of Marcellus downhole core samples
- Investigating the effect of matrix acidizing injection pressure on carbonate rich Marcellus shale core samples: an experimental study
- Bimetallic Mo-Co/ZSM-5 and Mo-Ni/ZSM-5 catalysts for methane dehydroaromatization: A study of the effect of pretreatment and metal loadings on the catalytic behavior
- Effect of Si/Al ratio of ZSM-5 support on structure and activity of Mo species in methane dehydroaromatization
- Nanoassembly of perovskite-based photocatalysts in a nanoconfined system for photocatalytic H2 production under visible light
- Experimental and DFT Study of Metal-Free Catalyst for Selective Oxidation of Biomass-Derived Molecule (HMF)
- Self-assembly of reversed bilayer vesicles through pnictogen bonding: water-stable supramolecular nanocontainers for organic solvents
- Cobalt(II)-Catalyzed Stereoselective Olefin Isomerization: Facile Access to Acyclic Trisubstituted Alkenes
- Hydrogen-Bond Synthon Preferences in Cocrystals of Acetazolamide
- Controlling thermal expansion within mixed cocrystals by tuning molecular motion capability
- Experimental and Computational Studies of Phosphine Ligand Displacement in Iridium-Pincer Complexes Employing Pyridine or Acetonitrile
- Verkade Base in FLP Chemistry-From Stoichiometric C-H Bond Cleavage to the Catalytic Dimerization of Alkynes
- Synthesis of metal iodates from an energetic salt
- Thermite reactivity with ball milled aluminum-zirconium fuel particles
- Multi-layer 3D chirality: new synthesis, AIE and computational studies
- Study of Physicochemical and Explosive Properties of a 2,4,6-Trinitrotoluene/Aniline Cocrystal Solvate
- Polynuclear lanthanide–diketonato clusters for the catalytic hydroboration of carboxamides and esters
- Effects of Solution Conditions on Polymorph Development in 2,4,6-Trinitrotoluene
- Hydroboration of Alkenes and Alkynes Employing Earth-Abundant Metal Catalysts
- Boronic, diboronic and boric acid esters of 1,8-naphthalenediol-synthesis, structure and formation of boronium salts
2019
- Effect of Hydration on Promoting Oxidative Reactions with Aluminum Oxide and Oxyhydroxide Nanoparticles
- A strategy for increasing the energy release rate of aluminum by replacing the alumina passivation shell with aluminum iodate hexahydrate (AIH)
- Plasma surface treatment of aluminum nanoparticles for energetic material applications
- Application of the pKa rule to synthesize salts of bezafibrate
- BPh3-Catalyzed [2+3] Cycloaddition of Ph3 PCCO with Aldonitrones: Access to 5-Isoxazolidinones with Exocyclic Phosphonium Ylide Moieties
- Unique supramolecular complex of diclofenac: structural robustness, crystal-to-crystal solvent exchange, and mechanochemical synthesis
- Pnictogen bonding with alkoxide cages: which pnictogen is best?
- Triple-Pnictogen Bonding as a Tool for Supramolecular Assembly
- Effects of dynamic pedal motion and static disorder on thermal expansion within halogen-bonded co-crystals
- Influence of Multiple Hydrogen Bonds on Thermal Expansion Within and Between Two-Dimensional Hydrogen-Bonded Sheets
- Multilayer 3D Chirality and Its Synthetic Assembly
- Highly reactive energetic films by pre-stressing nano-aluminum particles
- Hydroboration of Alkenes and Alkynes Employing Earth-Abundant Metal Catalysts
- Cooling-rate dependent single-crystal-to-single-crystal phase transition in an organic co-crystal
- Lewis acid base chemistry of Bestmann's ylide, Ph3PCCO, and its bulkier analogue, (cyclohexyl)3PCCO
- Synthesis, Characterization, Electrochemical Properties and Theoretical Calculations of (BIAN) Iron Complexes
- Lewis Acid Base Adducts of Zwitterionic Alkali Metal Methanides and Silanides With BH3
- Utilizing Autoxidation of Solvents To Promote the Formation of Uranyl Peroxide Materials
- Kinetic Study for Comprehensive Understanding of Solid-State Polymorphic Transitions of Nicotinamide/Pimelic Acid Cocrystals
2018
- Perylene Diimide Bearing Different Trialkyl Silyl Ethers: Impact of Asymmetric Functionalization on Self-Assembly into Nanostructures
- Enhancement of Molybdenum/ZSM‐5 Catalysts in Methane Aromatization by the Addition of Iron Promoters and by Reduction/Carburization Pretreatment
- Improving the Explosive Performance of Aluminum Nanoparticles with Aluminum Iodate Hexahydrate (AIH)
- Make Room for Iodine: Systematic Pore Tuning of Multivariate Metal-Organic Frameworks for the Catalytic Oxidation of Hydroquinones Using Hypervalent Iodine
- Nickel-Catalyzed Regioselective 1,4-Hydroboration of N-Heteroarenes
- Improved Synthesis of N-Methylcadaverine
- Impact of the presence of Mo carbide species prepared ex situ in Mo/HZSM-5 on the catalytic properties in methane aromatization
- Synthesis, characterization and reactivity of iridium pincer complexes
- Melting behavior of n-alkanes in anodic aluminum oxide (AAO) nanopores using Flash differential scanning calorimetry
- Diffusion and Selectivity of Water Confined within Metal–Organic Nanotubes
- Molecular Pedal Motion Influences Thermal Expansion Properties within Isostructural Hydrogen-Bonded Co-crystals
- A Pseudopericyclic [3,5]-Sigmatropic Rearrangement of a Coumarin Trichloroacetimidate Derivative
2017
- Replacing the Al2O3 Shell on Al Particles with an Oxidizing Salt, Aluminum Iodate Hexahydrate. Part I: Reactivity
- Replacing the Al2O3 Shell on Al Particles with an Oxidizing Salt, Aluminum Iodate Hexahydrate. Part II: Synthesis
- Interactions of Verkade's Superbase with Strong Lewis Acids: From Labile Mono- and Binuclear Lewis Acid–Base Complexes to Phosphenium Cations
- Spectral Analysis of the Uranyl Squarate and Croconate System: Evaluating Differences between the Solution and Solid-State Phases
- BIAN-Fe(η6-C6H6): Synthesis, characterization, and l-lactide polymerization
- Zwitterionic Alkali-Metal Silanides of Tripodal Ligand Geometry: Synthesis, Structure, and Lewis Acid–Base Chemistry
- Precise Steric Control over 2D versus 3D Self-Assembly of Antimony(III) Alkoxide Cages through Strong Secondary Bonding Interactions
- Characterization and photocatalytic behavior of 2,9-di(aryl)-1,10-phenanthroline copper(I) complexes
- Conductivity tuning of the ITO sol-gel materials by adjusting the tin oxide concentration, morphology and the crystalline size
- Spontaneous polarization field-enhanced charge separation for an iron oxide photo-catalyst
- Hierarchically 3D assembled strontium titanate nanomaterials for water splitting application
- Proximal sensor analysis of mine tailings in South Africa: An exploratory study
- Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach
- Asymmetric [3 + 2] Cycloaddition of Chiral N-Phosphonyl Imines with Methyl Isocyanoacetate for Accessing 2-Imidazolines with Switchable Stereoselectivity
- Synthesis and reactive characterization of aluminum iodate hexahydrate crystals [Al(H2O)6](IO3)3(HIO3)2
2016
- Sol–gel synthesis of a series of first row d-block ferrites via the epoxide addition method
- Superior white light emission and color tunability of tri-doped YBO3:Tb3+, Eu3+ and Dy3+ for white light emitting diodes
- Design, Synthesis, and Structural Characterization of a Bisantimony(III) Compound for Anion Binding and the Density Functional Theory Evaluation of Halide Binding through Antimony Secondary Bonding Interactions
- Synthesis, characterization and reactivity of iron- and cobalt-pincer complexes
- "Inverse" Frustrated Lewis Pairs – Activation of Dihydrogen with Organosuperbases and Moderate to Weak Lewis Acids
- Synthesis and structure of sterically overloaded tetra-coordinated yttrium and lanthanum disiloxides
- Unexpected isocyanide-based three-component bicyclization for the stereoselective synthesis of densely functionalized pyrano[3,4-c]pyrroles
- Asymmetric synthesis of homoallylic amines via 1,2-addition of Grignard reagent to aliphatic N-phosphonyl hemiaminal
2015
- Magnetic and optical properties of NaGdF4:Nd3+, Yb3+, Tm3+ nanocrystals with upconversion/downconversion luminescence from visible to the near-infrared second window
- In-situ crystal growth and photoluminescence properties of YBO3: Tb3+ microstructures
- Fe/Al binary oxide aerogels and xerogels for catalytic oxidation of aqueous contaminants
- Competitive Pseudopericyclic [3,3]- and [3,5]-Sigmatropic Rearrangements of Trichloroacetimidates
- Isomerization of Internal Alkynes to Iridium(III) Allene Complexes via C–H Bond Activation: Expanded Substrate Scope, and Progress towards a Catalytic Methodology
- Asymmetric Carbamoyl Anion Additions to Chiral N‑Phosphonyl Imines via the GAP Chemistry Process and Stereoselectivity Enrichments
- Catalytic Arylsulfonyl Radical Triggered 1,7-Enyne Bicyclizations
- Selective aldol condensation or cyclotrimerization reactions catalyzed by FeCl3
- Synthesis, Structure, and Reactivity of Zwitterionic Divalent Rare-Earth Metal Silanides
- Optimized procedure for sol–gel production of La2/3Ca1/3MnO3 thin films
- Iron-Catalyzed Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions
2014
- An efficient synthesis of 4-substituted coumarin derivatives via a palladium-catalyzed Suzuki cross-coupling reaction
- Asymmetric Carbamoyl Anion Additions to Chiral N-Phosphonyl Imines via the GAP Chemistry Process and Stereoselectivity Enrichments
- Synthesis of ZnO-CuO Nanocomposite Aerogels by the Sol-Gel Route
- Preparation–Morphology–Performance Relationships in Cobalt Aerogels as Supercapacitors
- Effect of Tb3+ concentration on the optical and vibrational properties of YBO3 tri-doped with Eu3+, Ce3+, and Tb3+
- Solvothermal Synthesis and Electrochemical Characterization of Shape-Controlled Pt Nanocrystals
- Formation of Iridium(III) Allene Complexes via Isomerization of Internal Alkynes
- A Well-Defined Monomeric Aluminum Complex as an Efficient and General Catalyst in the Meerwein–Ponndorf–Verley Reduction
- Four-component strategy for selective synthesis of azepino[5,4,3-cd]indoles and pyrazolo[3,4-b]pyridines
Department of Chemistry & Biochemistry
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