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Fall 2011

What's in Your Water?

Professor Audra Morse examines the fate of pharmaceuticals and personal care products in municipal wastewater systems.

Edited by Javad Hashemi and Jeff Sammons

Audra Morse

Audra N. Morse, an associate professor of civil and environmental engineering in the Whitacre College of Engineering, is studying the effects of land application of wastewater effluent and agricultural runoff. Specifically, she and her colleagues are seeking to learn the effects or fate of pharmaceuticals and personal care products (PPCPs) when they pass through municipal wastewater systems and are applied to land application sites (LAS).

Morse’s interest in the fate of PPCPs was initiated through a NASA grant that she received to examine amoxicillin and the potential impact of the reclamation of amoxicillin-tainted wastewater in space travel. Over time, this research has expanded to include a variety of PPCPs, and research funding has come from various sources, including the U.S. Environmental Protection Agency (EPA) and municipalities.

Recently, she has been examining the potential ecotoxicity and fate of amoxicillin, triclosan, estrogen, ibuprofen, caffeine, ciprofloxacin and many other common products and compounds that are part of our daily lives. These PPCPs are often introduced into the wastewater supply through residential sources.

Through a recent grant from the City of Lubbock, the EPA and Alan Plummer Associates, Morse is sampling wastewater in Lubbock. She is attempting to understand the natural sorption, degradation and impact that traditional wastewater treatment plants have on PPCPs by testing at the headworks, the waste-activated sludge (aeration basin), the chlorine contact chambers, the sludge train and the effluent application site. Morse has discovered that these compounds often travel through wastewater treatment plants unchanged, or minimally changed, being discharged into rivers, lakes or LAS.

Lubbock Land Application Site

The Lubbock Land Application Site (LLAS) is a 6,000-acre farm that distributes 13 million gallons of effluent annually to 31 center pivot systems. Wheat, corn, alfalfa and hay grazer are grown on the LLAS.

A Growing Problem

While these PPCPs often enter the environment in very small quantities, the continuous release of these compounds and chemicals, particularly at LAS, can contribute to significant deposits that may have lasting effects on plants, animals and humans through interactions with groundwater.

Studies have shown a negative impact on fish when exposed to wastewater effluent laced with PPCPs. However, it is not yet known if humans can be affected adversely, and how much impact is too much.

Additionally, it is not known how these PPCPs may behave over time and how they can potentially interact with one another. Federal, state and local governments regulate the release of many common elements and compounds, but the sheer number of PPCPs and the lack of knowledge about the relative toxicity or ecotoxicity of these compounds has been prohibitive in determining standards or regulations.

Morse, her colleagues – specifically Todd Anderson, professor in the Department of Environmental Toxicology at The Institute of Environmental and Human Health (TIEHH) – and her students are attempting to understand the level of sorption, bioremediation and degradation that occurs at LAS for common PPCPs. They are attempting to understand if plants and soils are playing a role in bioremediation or, if these compounds are persistent, plaguing the environment for generations to come.

Determining Degradation Rates

For many municipalities, the goal for wastewater is treatment, passage through the environment and eventual usage as a drinking water source. However, if PPCPs are present in this drinking water source, potential exists for their passage into the filtered drinking water supply.

wastewater

Treated wastewater, or effluent, is often discharged into streams, lakes, or other natural bodies of water.

Morse is discovering that determining a standard degradation time scale for many PPCPs may be difficult. She and her team have identified half-lives and time scales for many compounds by themselves and in a variety of soils, including saturated and non-saturated soils. However, they have discovered interferences between multiple compounds. As an example, estrogen and triclosan have a slower degradation time scale when combined, compared to the degradation of each compound independently. Now, Morse is examining why the removal efficiency decreases when they interfere with each other.

Understanding the interactions between compounds is critica. At any time wastewater may contain dozens of unique compounds interacting in various ways. Additionally, the efficiency of degradation and water treatment varies as the weather changes, and the introduction of many PPCPs can vary with the time of year to match cold and flu season or other factors.

Overall, minimizing the impact on the environment and maximizing our water resources is the goal. If we can safely process larger quantities of our wastewater and deposit that clean water into our rivers and lakes, farm fields, or drinking water, we can reduce our dependence on existing freshwater supplies and ensure safe environments for plants and wildlife.

Audra N. Morse

Morse joined the Department of Civil and Environmental Engineering in the Whitacre College of Engineering as an assistant professor in 2003. She received a Bachelor of Science and a Master of Environmental Engineering as well as a Doctor of Philosophy in Civil Engineering from Texas Tech University. She recently received the Texas Tech President's Excellence in Teaching Award for 2010 and the 2010 Chi Epsilon James M. Robbins Excellence in Teaching Award for the Southwest District.

Morse has received more than $1.3 million in research awards from NASA, the U.S. Department of Energy, the EPA, the Texas Department of Transportation and other organizations.

Javad Hashemi is the former Associate Dean of Research in the Whitacre College of Engineering at Texas Tech University and currently is Chair of the Department of Ocean and Mechanical Engineering at Florida Atlantic University. Jeff Sammons is Director of Marketing & Communications in the Whitacre College of Engineering at Texas Tech University. Morse photo courtesy Neal Hinkle.

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Sep 24, 2014